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A third obstacle is that zinc and copper ions exhibit the highest affinity for transition metal-binding sites and would occupy iron and manganese sites if the metals were present in freely exchangeable pools of similar concentrations ( THE FATE OF INTRACELLULAR IRON In mammals, iron enters the cell through a variety of transport systems, including the endosomal transporter DMT1 ( Figure 1 ) (reviewed in Zhao et al., 2010)