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Acknowledgments We wish to thank the Spanish network of Emerging crops for the diversification of agronomic and food systems through the use of crops with high nutritional value, project RED2022-134382-T funded by the Spanish Ministry of Science, Innovation and Universities and Carlos Garca and his team from the company Innovaciones Agroalimentarias S.L., Valladolid, Spain, for critical comments and stimulating discussions of the manuscript

As shown in Table 3, the intra-day and inter-day accuracy and precision for doxycycline at the LOQ concentration were within 20%, while those for the three other concentrations (LQC, MQC, HQC) were within 15%, meeting predefined acceptance criteria

ARE consensus 5-TGACTCAGC-3) at MMP-13, HO-1, and NQO1 gene promoters is increased +2.1, +1.8, +1.6 respectively at 10 M GHK-Cu (4h)